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Aromatic Substitution Electrophilic

Aromatic Substitution

Answers for Exercise

2. Nitration is substitution of a nitro group into the aromatic ring

3. By Freidel Crafts acylation.

4. In nitration it is the nitronium ion NO2+ . In sulphonation it can be SO3 or SO3H+. In halogenation it is an adduct with FeCl3 which is Cl+-Fe-Cl3. In alkylation it is an adduct if it is a primary alkyl halide or a carbo cation in the case of a secondary or tertiary alkyl halides , and in acylation it is the acylium ion.

5. A Lewis acid is an electron pair acceptor, it has a vacant orbital. Examples, BF3 or H+

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