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Curtin-Hammett Principle
Curtin Hammett Principle

But according to Curtin Hammett principle

“The product proportion does not depend on the ground state population of the two conformational isomers, but depends on the transition state energies of the two processes.”

Curtin Hammett Principle
Curtin Hammett Principle

P1 / P2 is the product proportion, k1and k2 are the rate constants of the two processes and K is the equilibrium constant for the equilibrium between the two isomers. [x] is the concentration of all other species.

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